LARHYSS JOURNAL 1112-3680 / 2521-9782
CHLORINATION OF AQUATIC HUMIC MATTER AND IMPACT OF THE PRESENCE OF AMMONIUM IONS
Abstract
The objective of this study is to examine the reactivity of the humic type organic material in the presence of chlorine as sodium hypochlorite. Humic substances are dissolved in water from different origins (distilled water, drilling Sidi Khellil and Ain Dalia Dam). The effect of ammonia is especially considered in these reactions.
The experimental tests focused on the determination of chlorine consumption potentials, the influence of the chlorination rate, as well as the influence of the initial ammonia concentration.
The results obtained show that the reactivity of chlorine with respect to humic substances, in the presence of ammonia, is very important both in distilled and in mineralized waters and whatever changes in various parameters.
For variable rates of introduced chlorine, a breakpoint characteristic curve is obtained, the latter being more pronounced in the case of distilled water and mineralized drilling water.
The involvement of ammonium ions in the chlorination reaction, and more particularly the value of the chlorine / ammonia ratio, can influence both the nature and the quantity of by-products formed (chloramines and organohalogen compounds).
Keywords
Full Text:
PDF (Français)References
ABARNOU A. (1981).Aspects chimiques de la chloration de l’eau de mer, Rapport de l’Institut Scientifique des pêches marines, Nantes, France, 92 p.
ACHOUR S., CHABBI F. (2014). Disinfection of drinking water-Constraints and optimization perspectives in Algeria, Larhyss Journal, N°19, pp.193-212.
ACHOUR S. (2012). Chloration des eaux de surface algériennes-Incidence sur la qualité physico-chimique des eaux, Ed. Presses Académiques Francophones, Sarrebruck, Allemagne, 137p.
ACHOUR S., GUERGAZI S. (2002).Incidence de la minéralisation des eaux algériennes sur la réactivité de composés organiques vis-à-vis du chlore, Revue des Sciences de l’Eau, Vol.15, N°3, pp. 649-668.
CIMETIERE. N., (2009). Etude de la décomposition de la monochloramine en milieu aqueux et réactivité avec des composés phénoliques, Thèse de Doctorat d’Université, Université de Poitiers, France, 165p.
CROUE J.P. (1987). Contribution à l’étude de l’oxydation par le chlore et l’ozone d’acides fulviques naturels extraits d’eaux de surface, Thèse de Docteur d’Université, Poitiers, France, 161p.
DEGREMONT (2005). Mémento technique de l’eau, Tomes 1et 2, 10éme Ed., Ed. Eyrolles, Paris, 1718p
DORE M. (1989), Chimie des oxydants- Traitement des eaux, Ed. Technique et Documentation-Lavoisier, Paris, 505 p.
HELLAL A., ACHOUR S. (2016). Effet des ions nitrites sur la réactivité de la tyrosine au cours de la chloration d’une eau superficielle algérienne. Larhyss Journal, N° 27, pp. 299-311.
MARTIN G. (1979). Le problème de l'azote dans les eaux, Ed. Technique et Documentation.- Lavoisier, Paris, Chap.18, pp.231-246.
MERLET N. (1986). Contribution à l’étude du mécanisme de formation des THM et des TOX non volatils lors de la chloration de molécules modèles. Thèse Doctorat Es-sciences physiques, Université de Poitiers, France, 139p.
NORWOOD D.L., CHRISTMAN R.F., HATCHER P.G. (1987). Structural characterization of aquatic humic material. 2. Phenolic content and its relationship to chlorination mechanism in an isolated aquatic fulvic acid, Environmental Science and Technology, Vol.21, Issue 8, pp.791-798.
RICHARDSON, S. D., PLEWA M.J., WAGNER E.D., SCHOENY R. AND DEMARINI D.M. (2007). Occurrence, genotoxicity, and carcinogenicity of regulated and emerging disinfection by-products in drinking water: A review and roadmap for research, Mutation Research-Reviews in Mutation Research, Vol.636, Issue 1-3, pp.178-242.
RODIER J., LEGUBE B., MERLET N., BRUNET R. (2009). L'analyse de l'eau, Eaux naturelles, Eaux résiduaires, Eau de mer: Analyse de l’eau, 9ème édition, Dunod, Paris, 1600p.
SOUFAN M. (2011). Oxydation par le chlore de composés pharmaceutiques, Thèse de Doctorat d’Université, Université de Poitiers, France, 155p.
Refbacks
- There are currently no refbacks.
This work is licensed under a Creative Commons Attribution 3.0 License.