REMOVAL OF PURPLE OF BROMOCRESOL FROM AQUEOUS SOLUTIONS BY BIOSORPTION ON A TROPICAL BIOMASS: THE TRIPLOCHITON SCLEROXYLON (AYUS) SAW

P. ABBA, M. PENGOU, S. BALKISSOU, Y. BADJOUKOUN, L.J. DELSIA, R. DANGA, W. ABDOUL

Abstract


The sawdust of ayous was used as an absorbent of the removal of purple of bromocrésol from aqueous solutions. The sawdust of ayous was treated by the sulphuric acid, the soda and the acetate of ethyl with an aim of stabilizing it and of increasing its capacity of adsorption; this enabled us to determine the pH of balance, and the pH of zero load. The biosorption was studied according to the time of contact, of the mass of biosorbant. The study of time of contact showed that balance is reached at the end of 10 min with a capacity of adsorption of 0.56 mg/g, that is to say a rate of elimination of 98.96 %. The kinetic study showed that the biosorption of purple of bromocresol follows better the model pseudo-second order with the coefficient of correlation of 0.999. The study of the isotherms of adsorption showed that the biosorption is described by the model of Langmuir with a coefficient of adsorption of 0.990.

Keywords


Biosorption, biosorbent, sawdust of ayous, purple of bromocresol, kinetics.

Full Text:

PDF (Français)

References


ABOUBAKAR, ABDOUL W., BOUBA L. (2017). Caractérisation des eaux de surface aux alentours d’une Société agro-industrielle de Maroua-Cameroun. Larhyss Journal, N° 29, pp.209-225.

ACHOUR S., GUERGAZI S., GUESBAYA N., SEGHAIRI N., YOUCEF L. (2002). Incidence des procédés de chloration, de floculation et d'adsorption sur l'évolution de composés organiques et minéraux des eaux naturelles, Larhyss Journal, N°1, pp.107 – 128.

AIEPS Artificial Intelligence Expert Prédictive System, (2003-2007) .Version 2.05. Ottawa (Ont.) : Environnement Canada, Division des substances existantes, Division des nouvelles substances. Modèle conçu par Stephen Niculescu. Accès : Environnement Canada, Division des substances existantes, Division des nouvelles substances.

ASADI F., SHARIATMADARI H., MIRGHAFFARI N. (2008). Modification of rice hull and sawdust sorption characteristics for remove heavy metals from synthetic solutions and wastewater, Journal of Hazardous Materials., Vol.154, pp. 451-458.

BENAÏSSA H., ELOUCHDI M.A. (2007). Removal of copper ions from aqueous solutions by dried sunflower leaves, Chemical Engineering and Processing., Vol.46, pp. 614–622

BRASIL J.L., EV R.R., MILCHAREK C.D., MARTINS L.C., PAVAN F.A., DOS SANTOS A.A., DIAS L.P., DUPONT J., ZAPATA C.P., NORENA E.C.(2006). Statistical design of experiments as a tool for optimizing the batch conditions to Cr(VI) biosorption on Araucaria angustifolia wastes. Journal of Hazardous Materials, B133, pp.143-153.

COLPINI L.M.S., ALVES H. J., ANDREO DOS SANTOS O. A., COSTA C.M.M, (2008). Discoloration and Degradation of Textile Dye Aqueous Solutionswith Titanium Oxide Catalysts Obtained by the Sol-gel Method, Dyes Pigment, Vol.76, pp. 525-529.

FIORENTIN L.D., TRIGUEROS D.E.G., MODENES A.N., ESPINOZA-QUIÑONES F.R., PEREIRA N.C., BARROS S.T.D., SANTOS O.A.A.(2010). Biosorption of Reactive Blue 5G Dye onto Drying Orange Bagasse in Batch System: Kinetic and Equilibrium Modelling, Chemistry Engineering Journal,Vol.163, pp. 68-77

FOSSOG V. (2008). Amelioraion par modification chimique de la biosorpion des ions mercuriques par la sciure du TriplochitonScleroxylon (Ayous), Mémoire de DEA, Université de Yaoundé I, Cameroun.

GÖK O., ÖZCAN A.S., ÖZCAN A.,(2010). Adsorption Behaviour of a Textile Dye of Reactive Blue 19 From Aqueous Solutions onto Modified Bentonite, Applied Surface Science, Vol.256, pp. 5439-5443.

GONG R.,LIU x.,FENG M., LIANG J.,CAI W. and LI N. (2008). Comparative study of methylene blue sorbed on crude and monosodium glutamate funtionalized Sawdust, Journal of Health Science, Vol.54, pp. 623-628.

GRAINDORGE J., LANDOT E. (2007). « La qualité de l’eau potable, techniques et responsabilités » Territorial Editions.

GUPTA V.K.,GUPTA B., RASTOGI A., AGARWAL S., NAYAK A.(2011). A Comparative Investigation on Adsorption Performances of Mesoporous Activated Carbon Prepared From Waste Rubber Tire and Activated Carbon for a Hazardous Azo Dye-Acid Blue 113, Journal of Hazardous Materials, Vol.186, pp.891-901.

GUPTA V.K., SHRIVASTAVA A.K., NEERAJ J. (2001). Biosorption of chromium (VI) from aqueous solutions by green algae Spirogyra species. Water Resource, Vol.35, pp.4079-4085.

HO Y.S, MCKAY G. (1999). Pseudo-second order model for sorption process, process biochemistry. Vol 34, pp. 456-556.

KHELIFI O., MEHREZ I., BEN SALAH W., BEN SALAH F., YOUNSI M., NACEF M., AFFOUNE A. M. (2016b). Etude de l’adsorption du Bleu de Methyléne (BM) à partir des solutions aqueuses sur un biosorbant préparé a partir des noyaux de datte Algérienne, LARHYSS Journal, N° 28, Issue 4, pp. 135‒148.

KHELIFI O., MEHREZ I., YOUNSI M., NACEF M., AFFOUNE A.M. (2008). Methyl orange adsorption on biosorbent derived from mango seed kernels, LARHYSS Journal, N° 36, pp. 145‒156

KENNE G.D. (2011). Biosorption du paraquat par les matériaux lignocellulosiques et élaboration des capteurs électrochimiques a film de sciures de bois, Thèse de doctorat, Université de Yaoundé 1, Cameroun

LOTFI M. et ADHOUM N.(2002). Modified activated carbon for the removal of copper, zinc, chromium and cyanide from wastewater. Separation and Purification Technology, pp.137-146.

MARIN J. (2001). Elimination de cations metalliques par la sciure de bois d’Epicéa-Valorisation de la sciure par modification chimique et greffage de molecules aux fonctions échangeuses d’ions, Thèse de doctorat, Université de Limoges, France .

Masschelein W. J. (1996). Processus unitaires du traitement de l’eau potable. Éditioncebedoc, Paris,

MELO J.S. et D’SOUZA S.F.(2004). Removal of chromium by mucilaginous seeds of Ocimum basilicum. Bioresource Technology ,Vol.92, 151-155.

NHAMEED B.H., (2008). Equilibrium and Kinetic Studies of Methyl Violet Sorption by Agricultural Waste, Journal of Hazardous Materials ,Vol.154, pp. 204-212

OZER A ., ALTUNDOGAN H.S., ERDEM M. et TUMEN F.(1997). A study on the Cr(VI) removal from aqueous solutions by steel wool. Environmental Pollution,Vol. 97,pp.107-112.

ÖZER Ayla, GÜRBÜZ GÖRKEM, AYLA C., ALIMLI B., BAHADIR K. (2008). Körbahti, “Investigation of nickel(II) biosorption on Enteromorpha prolifera: ptimization using response surface analysis”, Journal of Hazardous Materials., Vol.152, pp.778–788.

PADILLA A.P. et TAVANI E.L. (1999). Treatment of an industrial effluent by reverse osmosis. Desalination, Vol.129, pp.219-226.

PARK D., YUN Y.S. et PARK J.M. (2005). Use of dead fungal biomass for the detoxification of hexavalent chromium: screening and kinetics. Process Biochemistry, Vol.40, pp. 2559-2565.

RENGARAJ S., JOO C.K., KIM Y. et YI J. (2003). Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resins: 1200H, 1500H and IRN97H. Journal of Hazardous Materials. Vol.102,pp. 257-275.

SARIOGLU M., ATAY U. A.(2006). Removal of methylene blue by using biosolid, Global Nest Journal., Vol.8, pp.113- 120.

SEUMO P.(2008). Contribution à la valorisation de la sciure d’ayous : Etude de la biosorption des ions cuivriques par la sciure du TriplochitoScleroroxylon (Ayous), Mémoire de DEA, Université de Yaoundé I, Cameroun.

TONLÉ I., NGAMENI E.,TCHEUNO H., TCHIÉDA V., CARTERET C., WALCARIUS A. (2008). Sorption of methylene blue on an organoclay bearing thiol groups and application to electrochemical sensing of the dye, Talanta., Vol.74, pp. 489-497.

UCUN H ., BAYHAN Y.K., KAYA Y., CAKICI A. et ALGUR O.F.(2002). Biosorption of chromium(VI) from aqueous solution by cone biomass of Pinus sylvestris. Bioresource Technology, Vol.85, pp. 155-158.

VRTOCH U., AUGUSTIN J. (2009). Linear and non-linear regression analysis for the biosorption kenetic of methylene blue, Nova Biotechnologica., Vol.9,Issue 2, pp.199-204


Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution 3.0 License.